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Submitted publications

Impact of Polymer Bioconjugation on Protein Stability and Activity Investigated with Discrete Conjugates: Alternatives to PEGylation
J. Morgenstern, G. Gil Alvaradejo, N. Bluthardt, A. Beloqui, G. Delaittre,* J. Hubbuch*


Ultra-Fast Synthesis of Multivalent Radical Nanoparticles by Ring-Opening Metathesis Polymerization-Induced Self-Assembly
D. Le, M. Dilger, S. Diabaté, C. Weiss, G. Delaittre*


Controlled Manipulation of Enzyme Selectivity Through Immobilization-Driven Flexibility Constraints
C. Coscolín, A. Beloqui, M. Martínez-Martínez, R. Bargiela, G. Santiago, R. M. Blanco, G. Delaittre, C. Márquez-Álvarez, M. Ferrer*


Reactive Block Copolymers for Patterned Surface Immobilization with Sub-30 nm Spacing
H. Turgut, N. Dingenouts, V. Trouillet, P. Krolla-Sidenstein, H. Gliemann, G. Delaittre*

Published peer-reviewed publications

49. Intrinsically Fluorescent, Stealth Polypyrazoline Nanoparticles with Large Stokes Shift for in vivo Imaging
S. R. Mane, I-L. Hsiao, M. Takamiya, D. Le, U. Straehle, C. Barner-Kowollik,* C. Weiss,* G. Delaittre* Small 2018, in press.


48. Surface-Reactive Patchy Nanoparticles and Nanodiscs Prepared by Tandem Nanoprecipitation and Internal Phase Separation
D. Varadharajan, H. Turgut, J. Lahann, H. Yabu,* G. Delaittre* Adv. Funct. Mater. 2018, in press.


47. Nanostructured Thin Films of Moderately Functionalized PMMA-b-PS
H. Turgut, D. Varadharajan, N. Dingenouts, G. Delaittre* Macromol. Rapid Commun. 2018, DOI: 10.1002/marc.201800231.


46. The para-Fluoro–Thiol Reaction as an Efficient Tool in Polymer Chemistry
G. Delaittre,* L. Barner* Polym. Chem. 2018, 9, 2679–2684 (on the cover).


45. Maleimide End-Functionalized Poly(2-oxazoline)s by the Functional Initiator Route: Synthesis and (Bio)conjugation
G. Gil Alvaradejo, M. Glassner, R. Hoogenboom, G. Delaittre* RSC Adv. 2018,  8, 9471–9479.


44. A Simple Route to Highly Active Single-Enzyme Nanogels
A. Beloqui,* A. Yu. Kobitski, G. U. Nienhaus, G. Delaittre* Chem. Sci. 2018, 9, 1006–1013.


43. Nitrilotriacetic Amine-Functionalized Polymeric Core-Shell Nanoparticles as Enzyme Immobilization Supports
D. Keller, A. Beloqui, M. Martínez-Martínez, M. Ferrer, G. Delaittre* Biomacromolecules 2017, 18, 2777–2788.


42. 3D Laser Micro- and Nano-printing: Challenges for Chemistry
C. Barner-Kowollik,* M. Bastmeyer,* E. Blasco, G. Delaittre, P. Müller, B. Richter, M. Wegener* Angew. Chem. Int. Ed. 2017, 56, 15828–15845.



41. Stepwise Light-Induced Dual compaction of Single-Chain Nanoparticles
T. K. Claus, J. Zhang, L. Martin, M. Hartlieb, H. Mutlu, S. Perrier,* G. Delaittre,* C. Barner-Kowollik* Macromol. Rapid Commun. 2017, 38, 1700264.



40. Light-Driven Reversible Surface Functionalization with Anthracenes: Visible Light Writing and Mild UV Erasing
T. K. Claus, S. Telitel, A. Welle, M. Bastmeyer, A. P. Vogt, G. Delaittre,* C. Barner-Kowollik* Chem. Commun. 2017, 53, 1599–1602.


39. The para-Fluoro–Thiol Ligation in Water
H. Turgut, A. C. Schmidt, P. Wadhwani, A. Welle, R. Müller, G. Delaittre* Polym. Chem. 2017, 8, 1288–1293.


38. Accessing Libraries of Bifunctional Block Copolymers Using Two Distinct Pentafluorophenyl Moieties
D. Varadharajan, G. Delaittre* Polym. Chem. 2016, 7, 7488–7499.


37. Guiding Cell Attachment in Three-Dimensional Microscaffolds Selectively Functionalized with Two Distinct Adhesion Proteins
B. Richter, V. Hahn, S. Bertels, T. K. Claus, M. Wegener, G. Delaittre,* C. Barner-Kowollik,* M. Bastmeyer* Adv. Mater. 2016, DOI: 10.1002/adma.201604342.


36. Simultaneous Dual Encoding of 3D Structures via Light-induced Modular Ligation
T. K. Claus, B. Richter, V. Hahn, A. Welle,* S. Kayser, M. Wegener, M. Bastmeyer, G. Delaittre,* C. Barner-Kowollik* Angew. Chem. Int. Ed. 2016, 55, 3817–3822.


35. Single-Molecule Encapsulation: A Straightforward Route to Highly Stable and Printable Enzymes
A. Beloqui, S. Baur, V. Trouillet, A. Welle, J. Madsen, M. Bastmeyer, G. Delaittre* Small 2016, 12, 1716–1722.


34. On the Orthogonality of Two Thiol-Based Modular Ligations
H. Turgut, G. Delaittre* Chem. Eur. J. 2016, 22, 1511–1521.



33. Efficient Photochemical Approaches for Spatially Resolved Surface Functionalization
G. Delaittre,* A. S. Goldmann, J. O. Mueller, C. Barner-Kowollik* Angew. Chem. Int. Ed. 2015, 54, 11388-11403.



32. Cycloadditions in Modern Polymer Chemistry
G. Delaittre,* N. K. Guimard, C. Barner-Kowollik* Acc. Chem. Res. 2015, 48, 1296–1307.


31. Photolithographic Patterning of 3D-Formed Polycarbonate Films for Targeted Cell Guiding
A. F. Hirschbiel, S. Geyer, B. Yameen, A. Welle, S. Giselbrecht, S. Scholpp,* G. Delaittre,* C. Barner-Kowollik* Adv. Mater. 2015, 27, 2621–2626.

30. Fluorescent Polymers from Non-Fluorescent Photoreactive Monomers
J. O. Mueller, D. Voll, F. G. Schmidt, G. Delaittre,* C. Barner-Kowollik* Chem. Commun. 2014, 50, 15681–15684.



29. Direct Access to Dithiobenzoate RAFT Agent Fragmentation Rate Coefficients by ESR Spin-Trapping
K. Ranieri, G. Delaittre, C. Barner-Kowollik,* T. Junkers* Macromol. Rapid Commun. 2014, 35, 2023–2028.



28. SEC Analysis of Poly(Acrylic Acid) and Poly(Methacrylic Acid)
I. Lacík,* M. Stach, P. Kasák, V. Semak, L. Uhelská, A. Chovancová, G. Reinhold, P. Kilz, G. Delaittre, B. Charleux, I. Chaduc, F. D’Agosto, M. Lansalot, M. Gaborieau, P. Castignolles, R. G. Gilbert, Z. Szablan, C. Barner-Kowollik, P. Hesse, M. Buback Macromol. Chem. Phys. 2015, 1, 23-37.



27. Reversible Single-Chain Selective Point Folding via Cyclodextrin Driven Host/Guest Chemistry in Water 
J. Willenbacher, B. V. J. K. Schmidt, D. Schulze-Sünnighausen, O. Altintas, B. Luy, G. Delaittre, C. Barner-Kowollik* Chem. Commun. 2014, 50, 7056-7059.



26. (Meth)Acrylic Monomers with Heteroatom-Containing Ester Side Chains: A Systematic PLP-SEC and Polymerization Study 
A. P. Haehnel, M. Stach, A. Chovancová, J. M. Rueb, G. Delaittre, A. M. Misske, I. Lacík, C. Barner-Kowollik* Polym. Chem. 2014, 5, 862–873.



25. Three-Dimensional Microscaffolds Exhibiting Spatially Resolved Surface Chemistry 
B. Richter, T. Pauloehrl, J. Kaschke, D. Fichtner, J. Fischer, A. M. Greiner, D. Wedlich, M. Wegener, G. Delaittre,* C. Barner-Kowollik,* M. Bastmeyer* Adv. Mater. 2013, 25, 6117–6122.



24. Spatially Controlled Surface Immobilization of Non-Modified Peptides 
T. Pauloehrl, A. Welle, M. Bruns, K. Linkert, H. G. Börner, M. Bastmeyer, G. Delaittre, C. Barner-Kowollik* Angew. Chem. Int. Ed. 2013, 52, 9714–9718.


Surface Immobilization of Non-Modified Peptides


23. Nanoscale Organization of Proteins via Block Copolymer Lithography and Non-Covalent Bioconjugation 
I. C. Reynhout, G. Delaittre, H.-C. Kim, R. J. M. Nolte,* J. J. L. M. Cornelissen* J. Mater. Chem. B 2013, 1, 3026–3030.




22. Light-Induced Modular Ligation of Conventional RAFT Polymers 
K. K. Oehlenschlaeger, J. O. Mueller, N. B. Heine, M. Glassner, N. K. Guimard, G. Delaittre, F. G. Schmidt, C. Barner-Kowollik* Angew. Chem. Int. Ed. 2013, 52, 762–766.


Full size


21. (Bio)molecular Surface Patterning by Phototriggered Oxime Ligation 
T. Pauloehrl, G. Delaittre, M. Bruns, M. Meißler, H. G. Börner, M. Bastmeyer, C. Barner-Kowollik* Angew. Chem. Int. Ed. 2012, 51, 9181–9184.



20. Polymerization-Induced Self-Assembly: From Soluble Macromolecules to Block Copolymer Nano-Objects in One Step 
B. Charleux,* G. Delaittre, J. Rieger, F. D’Agosto Macromolecules 2012, 45, 6753–6765. Featured on the cover.



19. (Ultra)Fast Catalyst-Free Macromolecular Conjugation in Aqueous Environment 
M. Glassner, G. Delaittre, M. Kaupp, J. P. Blinco, C. Barner-Kowollik* J. Am. Chem. Soc. 2012, 134, 7274-7277.



18. Chemical Approaches to Synthetic Polymer Surface Biofunctionalization for Targeted Cell Adhesion Using Small Binding Motifs 
G. Delaittre,* A. M. Greiner, T. Pauloehrl, M. Bastmeyer,* C. Barner-Kowollik* Soft Matter 2012, 8, 7323–7347.



17. Thioketone-Mediated Polymerization with Dithiobenzoates: Proof for the Existence of Stable Radical Intermediate in RAFT Polymerization 
T. Junkers,* G. Delaittre, R. Chapman, F. Günzler, E. Chernikova, C. Barner-Kowollik* Macromol. Rapid Commun. 2012, 33, 984990.




16. Synthesis by Nitroxide-Mediated Aqueous Dispersion Polymerization, Characterization, and Physical Core-Crosslinking of pH- and Thermoresponsive Dynamic Diblock Copolymer Micelles 
G. Delaittre,* M. Save, M. Gaborieau, P. Castignolles, J. Rieger, B. Charleux* Polym. Chem. 2012, 3, 15261538.




15. Photo-Induced Macromolecular Functionalization of Cellulose via Nitroxide Spin Trapping 
G. Delaittre, M. Dietrich, J. P. Blinco, A. Hirschbiel, M. Bruns, L. Barner, C. Barner-Kowollik* Biomacromolecules 2012, 13, 1700–1705.



14. Acrylamide-Based Copolymers Bearing Photo-Releasable Thiols for Subsequent Thiol-Ene Functionalization 
G. Delaittre, T. Pauloehrl, M. Bastmeyer, C. Barner-Kowollik* Macromolecules 2012, 45, 17921802.



13. Adding Spatial Control to Click Chemistry: Light-Triggered Diels-Alder Surface (Bio)functionalization at Ambient Temperature 
T. Pauloehrl, G. Delaittre, V. Winkler, A. Welle, M. Bruns, H. G. Börner, A. M. Greiner, M. Bastmeyer, C. Barner-Kowollik* Angew. Chem. Int. Ed. 2012, 51, 1071–1074.



12. Photoclickable Surfaces for Profluorescent Covalent Polymer Coatings 
M. Dietrich, G. Delaittre, J. P. Blinco, A. J. Inglis, M. Bruns, C. Barner-Kowollik* Adv. Funct. Mater. 2012, 22, 304312.



11. Ambient Temperature Polymer Modification by In-situ Phototriggered Deprotection and Thiol-Ene Chemistry 
T. Pauloehrl, G. Delaittre, M. Bastmeyer, C. Barner-Kowollik* Polym. Chem. 2012, 3, 17401749.







10. Solution Scattering Studies on a Virus Capsid Protein as a Building Block for Nanoscale Assemblies 
M. Comellas-Aragonès, F. Sikkema, G. Delaittre, A. E. Terry, S. M. King, D. Visser, R. M. Heenan, R. J. M. Nolte, J. J. L. M. Cornelissen, M. C. Feiters* Soft Matter 2011, 7, 1138011391.







9. Nitroxide-Mediated Living/Controlled Polymerization of N,N-Diethylacrylamide 
G. Delaittre,* J. Rieger, B. Charleux* Macromolecules 2011, 44, 462–470.







8. Amine-Reactive Polymeric Nanoparticles for Potential Bioconjugation 
G. Delaittre,* G. Justrib?-Hernández, R. J. M. Nolte, J. J. L. M. Cornelissen* Macromol. Rapid Commun. 2011, 32, 19–24.







7. Preparation of Hybrid Latex Particles and Core-Shell Particles through the Use of Controlled Radical Polymerization Techniques in Aqueous Media 
B. Charleux,* F. D’Agosto, G. Delaittre Adv. Polym. Sci. 2011, 233, 125–183.



6. Cascade Reactions in an All-Enzyme Nanoreactor 
G. Delaittre, I. C. Reynhout, J. J. L. M. Cornelissen,* R. J. M. Nolte* Chem. Eur. J. 2009, 15, 12600–12603.






5. Formation of Polymer Vesicles by Simultaneous Chain Growth and Self-Assembly of Amphiphilic Block Copolymers 
G. Delaittre,* C. Dire, J. Rieger, J.-L. Putaux, B. Charleux* Chem. Commun. 2009, 2887–2889.







4. Kinetics of in situ Formation of Poly(Acrylic Acid)-b-Polystyrene Amphiphilic Block Copolymers via Nitroxide-Mediated Controlled Free-Radical Emulsion Polymerization. Discussion on the Effect of Compartmentalization on the Polymerization Rate 
G. Delaittre, B. Charleux* Macromolecules 2008, 41, 2361–2367.







3. Nitroxide-Mediated Aqueous Dispersion Polymerization: From Water-Soluble Macroalkoxyamine to Thermosensitive Nanogels 
G. Delaittre, M. Save, B. Charleux* Macromol. Rapid Commun. 2007, 28, 1528–1533.







2. Aqueous Suspension of Amphiphilic Diblock Copolymer Nanoparticles Prepared in situ from a Water-Soluble Poly(sodium acrylate) Alkoxyamine Macroinitiator 
G. Delaittre, J. Nicolas, C. Lefay, M. Save, B. Charleux* Soft Matter 2006, 2, 223–231.







1. Surfactant-Free Synthesis of Amphiphilic Diblock Copolymer Nanoparticles via Nitroxide-Mediated Emulsion Polymerization 
G. Delaittre, J. Nicolas, C. Lefay, M. Save, B. Charleux* Chem. Commun. 2005, 614–616.







Photoreactive Monomers US9315445 (B2), 13th March 2014
Photoreaktive Monomere EP2708528 (A1), 19th March 2014
D. Urban, U. Licht, C. Barner-Kowollik, G. Delaittre, E. Frick

Photoreactive Polymer US9034938 (B2), 13th March 2014
Photoreaktives Polymer  EP2708580 (B1), 19th March 2014
D. Urban, U. Licht, T. Smit, C. Barner-Kowollik, G. Delaittre, E. Frick

Method for Preparing Microgel Particles by Controlled Radical Polymerization in an Aqueous Dispersion using Nitroxides as Control Agents.
B. Charleux, G. Delaittre, M. Save, S. Magnet WO/2008/095814, August 14th 2008.


Book chapters


Nitroxide-Mediated Polymerization in Dispersed Media
G. Delaittre in Handbook of Nitroxide Mediated Polymerization, Ed.: D. Gigmes, Royal Society of Chemistry. In press.


Modification of Polymer Surfaces for Biofunctionalization
G. Delaittre in Design of Polymeric Platforms for Selective Biorecognition, Eds.: J. Rodriguez-Hernandez and A. Lopez-Cortajarena, Springer Ed. USA. 2015.


Advanced Strategies for Spatially Resolved Surface Design via Photochemical Methods
A. S. Goldmann, G. Delaittre, J. O. Mueller, C. Barner-Kowollik in Dyes and Chromophores in Polymer Science, Eds: J. Lalevée and J.-P. Fouassier, John Wiley & Sons, Inc., 2015.


Elucidation of Reaction Mechanisms and Polymer Structure: Living/Controlled Radical Polymerization
C. Barner-Kowollik, G. Delaittre, T. Gründling, T. Paulöhrl in Mass Spectrometry in Polymer Chemistry, Eds.: C. Barner-Kowollik, T. Gründling, J. Falkenhagen, S. Weidner, Wiley-VCH, Weinheim, Germany, 2011.




Last update: July 03, 2018